Optimization of Preparative Separation and Purification of Total PolyphenoJs from Sargassum tenerrimum by Column Chromatography     

Samee Haider  LI Zhenxing  LIN Hong  Khalid Jamil 《青岛海洋大学学报(英文版)》2009,(4):425-430

Polyphenols from the ethanol extracts of Sargassum tenerrimum （ST） with potent antiallergic effects were studied to optimize separation process through column chromatography. The adsorption and desorption characteristics of three widely used adsorbents： macroporous resin, silica gel, and polyvinylpolypyrrolidone （PVPP）, were critically evaluated respectively and studied for the optimization of preparative separation of polyphenols. Static operations on these adsorbents showed that macroporous resin had the best adsorption and desorption capability among the three adsorbents. Dynamic adsorption and desorption with macroporous resin packed column were also conducted to optimize the parameters such as： with the optimal values shown in brackets, the concen- tration of extract solution （4 times diluted）, pH value （6-7）, adsorption speed （3BVh-1, bed volumes/per hour）, concentration of ethanol （80%）, elution speed （3 BV ht） and elution volume （7 BV）. The chromatographic process so optimized gave a purity of 62.43% from the crude polyphenols, providing a promising basis for large scale preparation of bioactive polyphenols upon further scaling up tests.  相似文献   

Instabilities in a nonstationary model of self-gravitating disks. III. The phenomenon of lopsidedness and a comparison of perturbation modes     

K. T. Mirtadjieva  S. N. Nuritdinov  J. K. Ruzibaev  Muhammad Khalid 《Astrophysics》2011,54(2):184-202

This is an examination of the gravitational instability of the major large-scale perturbation modes for a fixed value of the azimuthal wave number m = 1 in nonlinearly nonstationary disk models with isotropic and anisotropic velocity diagrams for the purpose of explaining the displacement of the nucleus away from the geometric center (lopsidedness) in spiral galaxies. Nonstationary analogs of the dispersion relations for these perturbation modes are obtained. Critical diagrams of the initial virial ratio are constructed from the rotation parameters for the models in each case. A comparative analysis is made of the instability growth rates for the major horizontal perturbation modes in terms of two models, and it is found that, on the average, the instability growth rate for the m = 1 mode with a radial wave number N = 3 almost always has a clear advantage relative to the other modes. An analysis of these results shows that if the initial total kinetic energy in an isotropic model is no more than 12.4% of the initial potential energy, then, regardless of the value of the rotation parameter Ω, an instability of the radial motions always occurs and causes the nucleus to shift away from the geometrical center. This instability is aperiodic when Ω = 0 and is oscillatory when Ω ≠ 0 . For the anisotropic model, this kind of structure involving the nucleus develops when the initial total kinetic energy in the model is no more than 30.6% of the initial potential energy.  相似文献   

Mesoscale and Nutrient Conditions Associated with the Massive 2008 Cochlodinium polykrikoides Bloom in the Sea of Oman/Arabian Gulf     

Adnan R. Al-Azri  Sergey A. Piontkovski  Khalid A. Al-Hashmi  Joaquim I. Goes  Helga do R. Gomes  Patricia M. Glibert 《Estuaries and Coasts》2014,37(2):325-338

Cochlodinium polykrikoides formed large blooms in the coastal waters of Oman from October 2008 through mid-January 2009, and satellite images from Aqua-MODIS and region-wide reports suggest that this bloom was found throughout the Arabian Gulf and Sea of Oman for more than 10 months. The unusual occurrence of this species appears to have supplanted the more regularly occurring bloom species, Noctiluca scintillans, in 2008–2009. For the first 2 weeks of the coastal Omani bloom, C. polykrikoides abundance was near monospecific proportions, with cell densities ranging from 4.6?×?10³ to 9?×?10⁶ cells L^?1 and very high levels of chlorophyll a (78.0 μg L^?1) were also recorded. The regional progression of the bloom likely began with stronger than normal upwelling along the Iranian and northern Omani coasts during the southwest monsoon in late summer, followed by discharge of unusually warm coastal plume water along the coast of Oman with the reversal of monsoonal winds in late October. The occurrence and persistence of high densities of C. polykrikoides in Oman coastal water were also significantly influenced by an elevated nutrient load and warmer than normal temperatures. Concentrations of nutrients, especially NH₄ ⁺, urea, PO₄ ^3?, and organic nitrogen and phosphorus, were manyfold higher than observed in the year prior or since. These findings suggest that mesoscale features were important in bloom dynamics more regionally, but locally the bloom was sustained by nutrient enrichment supplemented by its mixotrophic capabilities.  相似文献   

Characteristics of lipid tracer compounds transported to the Arabian Gulf by runoff from rivers and atmospheric dust transport     

Ahmed I. Rushdi  Khalid F. Al-Mutlaq  Bernd R. T. Simoneit  Adnan Al-Azri  Ali A. Z. DouAbul  Sheikha Al-Zarban  Faiza Al-Yamani 《Arabian Journal of Geosciences》2010,3(2):113-131

River runoff and atmospheric fallout (dust and air particulate matter) are major input sources of natural and anthropogenic terrestrial organic and inorganic components to the Arabian seas. In this study, we report on the various lipid tracer compounds that might be transported to the Arabian Gulf by rivers, dust, and air particulate matter. These are based on geochemical analysis of sediment, dust, and particulate samples collected from Iraq, Kuwait, and Saudi Arabia. The samples were extracted with a dichloromethane/methanol mixture and analyzed by gas chromatography-mass spectrometry. The extractable organic compounds (lipids) in the samples include n-alkanes, n-alkanoic acids, n-alkanols, methyl n-alkanoates, steroids, triterpenoids, carbohydrates, and petroleum hydrocarbons. The steroids and triterpenoids were major components in river and wetland samples. The major sources of these lipids were from natural vegetation, microbial (plankton and bacteria) residues in the sediments, sand, and soils, with some contribution from anthropogenic sources. Accordingly, these sources could be major inputs to the Arabian seas besides the autochthonous marine products. Future studies of the organic and inorganic biogeochemistry on river, dust, and coastal areas are needed to characterize the various regional sources, transformation, and diagenetic processes of the organic matter en route to the marine environment.  相似文献   

Optimization of preparative separation and purification of total polyphenols from Sargassum tenerrimum by column chromatography     

Samee Haider  Zhenxing Li  Hong Lin  Khalid Jamil 《中国海洋大学学报(英文版)》2009,8(4):425-430

Polyphenols from the ethanol extracts of Sargassum tenerrimum (ST) with potent antiallergic effects were studied to optimize separation process through column chromatography. The adsorption and desorption characteristics of three widely used adsorbents: macroporous resin, silica gel, and polyvinylpolypyrrolidone (PVPP), were critically evaluated respectively and studied for the optimization of preparative separation of polyphenols. Static operations on these adsorbents showed that macroporous resin had the best adsorption and desorption capability among the three adsorbents. Dynamic adsorption and desorption with macroporous resin packed column were also conducted to optimize the parameters such as: with the optimal values shown in brackets, the concentration of extract solution (4 times diluted), pH value (6–7), adsorption speed (3 BV h⁻¹, bed volumes/per hour), concentration of ethanol (80%), elution speed (3 BV h⁻¹) and elution volume (7 BV). The chromatographic process so optimized gave a purity of 62.43% from the crude polyphenols, providing a promising basis for large scale preparation of bioactive polyphenols upon further scaling up tests.  相似文献   

Groundwater budget for the upper and middle parts of the River Gash Basin, eastern Sudan     

Abdalla Eltom Mohamed Elsheikh  Khalid A. Elsayed Zeinelabdein  Shaza A. Elobeid 《Arabian Journal of Geosciences》2011,4(3-4):567-574

The River Gash Basin is filled by the Quaternary alluvial deposits, unconformably overlying the basement rocks. The alluvial deposits are composed mainly of unconsolidated layers of gravel, sand, silt, and clays. The aquifer is unconfined and is laterally bounded by the impermeable Neogene clays. The methods used in this study include the carry out of pumping tests and the analysis of well inventory data in addition to the river discharge rates and other meteorological data. The average annual discharge of the River Gash is estimated to be 1,056?×?10⁶ m³ at El Gera gage station (upstream) and 587?×?10⁶ m³ at Salam-Alikum gage station (downstream). The annual loss mounts up to 40% of the total discharge. The water loss is attributed to infiltration and evapotranspiration. The present study proofs that the hydraulic conductivity ranges from 36 to 105 m/day, whereas the transmissivity ranges from 328 to 1,677 m²/day. The monitoring of groundwater level measurements indicates that the water table rises during the rainy season by 9 m in the upstream and 6 m in the midstream areas. The storage capacity of the upper and middle parts of the River Gash Basin is calculated as 502?×?10⁶ m³. The groundwater input reach 386.11?×?10⁶ m³/year, while the groundwater output is calculated as 365.98?×?10⁶ m³/year. The estimated difference between the input and output water quantities in the upper and middle parts of the River Gash Basin demonstrates a positive groundwater budget by about 20?×?10⁶ m³/year  相似文献   

Application of the subjective vertical-horizontal-conflict physiological motion sickness model to the field trials of contemporary vessels     

Hassan Khalid  Osman Turan 《Ocean Engineering》2011,38(1):22-33

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Embryonic development of Pelteobagrus fulvidraco （Richardson, 1846）     

王卫民  Khalid ABBAS  严安生 《中国海洋湖沼学报》2006,24(4):378-383

1 INTRODUCTION Pelteobagrus fulvidraco (Richardson, 1846) or yellow catfish is slender and scaleless with a gently sloping dorsal profile from anterior to posterior. It is generally black-brown to black-yellow on the back, light yellow on the belly, with …  相似文献   

Effects of Replacing Fishmeal with Animal By-products Meal Supplementation in Diets on the Growth and Nutrient Utilization of Mangrove Red Snapper   总被引：1，自引：0，他引：1  

Khalid Jamil Ghulam Abbas Rukhsana Akhtar LIN Hong LI Zhenxing 《中国海洋大学学报(英文版)》2007,6(3):292-298

A feeding trial was conducted for 75 d to evaluate the nutritive value of a mixture of animal by-products(MAB) as a possible protein source in diets for juvenile mangrove red snapper,Lutjanus argentimaculatus(mean initial body weight,30 g). Fish were fed one of five isonitrogenous diets(40% crude protein) replacing 0,25%(MAB25),50%(MAB50),75%(MAB75) and 100%(MAB100) of fish meal protein with similar percentages of MAB. The MAB consisted of 25% cow liver meal,20% leather meal,20% meat and bone meal,15% blood meal,10% APC(poultry feather meal),8% poultry manure dried,1.5% choline and 0.5% chromic oxide. After 75 d of feeding,fish fed with diets MAB50,MAB75 and MAB100 exhibited significantly lower growth per-formance than that of fish fed with control and MAB25 diets. The optimum level of MAB was estimated to be 23%. Replacement of fish meal by MAB23% showed the following performance:maximum weight gain,510%;SGR,2.39% and FCE,2.83%. The MAB substitution up to 75% of fish meal protein in diets did not show differences in apparent protein digestibility(83.6% for MAB25,79.2% for MAB50,78.7% for MAB75) compared with control(83.4%),whereas in MAB100 group digestibility(65.3%) was sig-nificantly lower than in other groups. The apparent phosphorus absorption of test diet groups was significantly higher(37.1% for MAB25,28.5% for MAB50,55.6% for MAB75 and 54.5% for MAB100) than that of control(11.2%). The levels of protein and ash in the whole body,carcass and viscera increased as MAB substitution in diets increased,whereas lipids and moisture remained con-sistent among all treatment groups. These results showed that approximately 23% of fish meal protein could be replaced by a mixture of animal by-products for juvenile snapper growing from 30 g to 167 g in 75 d without compromising growth performance and feed efficiency.  相似文献   

An ActiveX control for embedding GPS capability in custom applications     

Khalid Amin Khan  Gulraiz Akhter  Zulfiqar Ahmad 《GPS Solutions》2011,15(4):433-439

An ActiveX GPS control is presented which can be used to develop software applications with GPS functionality. It translates the NMEA 0183 interface GPS instructions and triggers event procedures which are used by applications to access the GPS data. It provides position data in the form of geographic coordinates as well as Universal Transverse Mercator (UTM) projected coordinates. This control is recommended for the development of general purpose GPS-enabled applications which do not require a high level of accuracy. A Visual Basic project is also included to demonstrate the use of various features of this control. Finally, some real-time software applications are discussed which have been developed using this control. These applications include static point averaging; path tracking; and imagery-based position mapping.  相似文献